There's your problem then, you have mods installed in 2 different locations. Either it's:
C:\Users\Numpa\AppData\Local\ModOrganizer\Skyrim\mods\Dual Sheath Redux\SkyProc Patchers\Dual Sheath Redux Patch
D:\SteamLibrary\steamapps\common\Skyrim\ModOrganizer\mods\Dual Sheath Redux\SkyProc Patchers\Dual Sheath Redux Patch
I'd say at some point you have either had mods installed in the default MO locations and then made changes to the settings and saved them elsewhere or you have two separate MO installations and they are trying to use the same settings.
The 2nd error message is saying it can't access the patcher so it is either not enabled in the left-hand pane, not actually installed where you think or it isn't installed at all.
I'd take some time and do some housekeeping on your gaming system and move MO out of whereever it is installed and install it into its own folder such as "C:\Games\Tools\MO" or similar. Then have your downloads, mods and profiles in folders under that.
This does two things.
One, it shortens the path to executables and this is always good, as you will eventually come across an exceeding of path limit error.
Two, it avoids any UAC issues stemming from Windows wanting to control your system.